WARNING!! THIS EXPERIMENT IS PARTICULARLY DANGEROUS!! (No kidding.) This experiment is for advanced students.


We’ve created a video that shows you how to safely do this experiment, although if you’re nervous about doing this one, just watch the video and skip the actual experiment.


Bromine is a particularly nasty chemical, so be sure to very carefully follow the steps we’ve outlined in the video. You MUST do this experiment outdoors. We’ll be making a tiny amount to show how the chemical reactions involving bromine work.


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Isn’t it interesting how many ways we can use the same techniques and, by just changing a few chemicals, we can learn about so many different chemical reactions? This lab is similar in technique to the Generating Hydrochloric Acid lab. Using the same techniques, we will produce hydrogen bromide.


Hydrogen bromide (HBr) was used as a sedative in the late 1800s and early 1900s. Once they found out how poisonous it really was  (after enough people became blind and/or dead), someone had the wonderful idea that maybe we shouldn’t use it anymore. It was also used to control epilepsy until the substitute Phenobarbital came on the scene in 1911. HBr is still used to treat epilepsy in dogs. In cats HBr causes inflammation of the lungs and makes for a very unhappy cat.


Materials:


  • Alcohol burner
  • Lighter
  • Wire screen
  • Tripod stand
  • Glass jar
  • Rubber tubing
  • 900 Glass tubing
  • One-hole rubber stopper
  • Chemistry stand
  • Test tube holder
  • Test tube
  • Potassium bromide (KBr) (MSDS)
  • Sodium hydrogen sulfate (NaHSO4) (MSDS) Sodium hydrogen sulfate is very toxic. Respect it, handle it carefully and responsibly. Do not take it for granted.
  • Burette
  • Water
  • Sodium carbonate (Na2CO3) (MSDS)
  • Silver nitrate (AgNO3) (MSDS)

NOTE: Be very careful when handling the sodium hydrogen sulfate – it’s highly corrosive and dangerous when wet.  Handle this chemical only with gloves, and be sure to read over the MSDS before using.


Maintain good and proper lab techniques. We are working with some nasty stuff in this lab. We need to perform this lab outdoors if possible, or indoors with lots of ventilation. The reaction advances in stages:


  • Bubbles in the burette tell us the reaction is occurring.
  • Brown streaks will appear in the water contained in the glass jar as gas collects there.
  • Brown vapor will begin to appear in the test tube. When the reaction is complete, the test tube will contain lots of brown vapor.

After we produce HBr, we will perform a number of tests to see if it is an acid or a base.


  1. Test contents of test tube with blue litmus paper. Red color change indicates an acid.
  2. Add baking soda to the HBr. Bubbles and the solution turning white. HBr is an acid in this test because it is obviously reacting with a base.
  3. If a magnesium strip placed in the HBr corrodes, or starts to dissolve, then HBr is an acid.
  4. With the addition of silver nitrate to the HBr, if a white cloudiness occurs and crystals form in the bottom of the test tube, then HBr is an acid.

C3000: Experiments 134-138


Download Student Worksheet & Exercises


Here’s what’s going on in this experiment:


KBr    +    NaHSO4 –>    HBr    +    KNaSO4


Potassium bromide and sodium hydrogen sulfate, when heated, produce hydrogen bromide and potassium sodium sulfate.


Cleanup: We are going to clean everything thoroughly after we finish the lab. After cleaning with soap and water, rinse thoroughly. Chemists use the rule of “three” in cleaning glassware and tools. After washing, chemists rinse out all visible soap and then rinse three times more.


Storage: Place cleaned tools and glassware in their respective storage places.


Disposal: Liquids can be washed down the drain. Solids are thrown in the trash.


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WARNING!! THIS EXPERIMENT IS PARTICULARLY DANGEROUS!! (No kidding.) This experiment is for advanced students.


We’ve created a video that shows you how to safely do this experiment, although if you’re nervous about doing this one, just watch the video and skip the actual experiment.


The gas you generate with this experiment is lethal in large doses, so you MUST do this experiment outdoors.  We’ll be making a tiny amount to show how the chemical reactions of chlorine and hydrogen work.


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Hydrochloric acid is a strong acid. It is highly corrosive, which means that this acid will destroy or irreversibly damage another substance it comes in contact with. Simple terms….it is pretty nasty, so take special care when working with or around it.


HCl is used in processing leather, cleaning products, and in the food industry. We are most familiar with HCl in the form of Gastric Acid. HCl is in gastric acid and is one of the main ingredients in our stomach to aid in digestion of our food. In our lab we will produce hydrogen chlorine gas and add water to turn change it into hydrochloric acid.


Materials:


  • Glass jar
  • 900 bend glass tubing
  • One-hole rubber stopper
  • Chemistry stand
  • Wire mesh
  • 2 Test tubes
  • Test tube clamp
  • Alcohol burner
  • Lighter
  • Tripod stand
  • Sodium hydrogen sulfate (MSDS) Sodium hydrogen sulfate is very toxic. Respect it, handle it carefully and responsibly. Do not take it for granted.
  • Salt
  • One-hole cork
  • Medicine dropper
  • Water
  • Solid rubber stopper

NOTE: Be very careful when handling the sodium hydrogen sulfate – it’s highly corrosive and dangerous when wet.  Handle this chemical only with gloves, and be sure to read over the MSDS before using.


Perform this experiment outdoors. If that is not a possibility, and you must do it inside, open doors and windows to provide lots of ventilation. Hydrogen chlorine gas inhalation can be fatal, but we are only producing a very small amount.


There are many steps in this lab, so go slow and steady. Read the lab over several times so you are sure what is going on and what is happening next.


When we shake the sodium hydrogen sulfate and the salt together in a stoppered test tube, we are trying to produce a heterogeneous mixture. Heterogeneous is a scientific word that means substance are mixed all together to be as one. A sample taken from one spot in the mixture should be the same as a sample taken from any other spot in the mixture.


At some point in this lab, we need to point the test tube containing the reaction slightly down. This is so the hydrogen chlorine gas can flow downhill. The gas is denser than air, so it will sink to the bottom of anything air filled…..like a room or a test tube.


Hydrogen chloride gas is poisonous – DO NOT INHALE!


When the medicine dropper / cork tool is placed in the water, water will be sucked up into the test tube. The water combines with the hydrogen chlorine gas to create hydrochloric acid.


A double replacement chemical reaction will take place in this experiment. A free hydrogen ion (+) and a free sodium ion (+) will be produced. Because their charges are alike, they cannot bond, but they can take each other’s place. The spots they each left are negatively charged after the hydrogen and sodium have departed. Opposites attract, and they reorganize into a double replacement reaction.


C3000: Experiment 112


Download Student Worksheet & Exercises


Here’s what’s going on in this experiment:


NaCl  +  NaHSO4 –>  HCl  +  Na2SO4


Salt is combined with sodium hydrogen sulfate and heated to produce hydrochloric acid and sodium sulfate


Cleanup: We are going to clean everything thoroughly after we finish the lab. After cleaning with soap and water, rinse thoroughly. Chemists use the rule of “three” in cleaning glassware and tools. After washing, chemists rinse out all visible soap and then rinse three times more.


Storage: Place cleaned tools and glassware in their respective storage places.


Disposal: Our HCl needs to be neutralized before disposal. Put a bit of baking soda into the test tube. The contents should bubble as the neutralization is taking place. After neutralization, the liquid is safe, and can be washed down the drain. Solids are thrown in the trash.


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If you’ve ever had a shot, you know how cold your arm feels when the nurse swipes it with a pad of alcohol. What happened there? Well, alcohol is a liquid with a fairly low boiling point. In other words, it goes from liquid to gas at a fairly low temperature. The heat from your body is more then enough to make the alcohol evaporate.


As the alcohol went from liquid to gas it sucked heat out of your body. For things to evaporate, they must suck in heat from their surroundings to change state. As the alcohol evaporated you felt cold where the alcohol was. This is because the alcohol was sucking the heat energy out of that part of your body (heat was being transferred by conduction) and causing that part of your body to decrease in temperature.


As things condense (go from gas to liquid state) the opposite happens. Things release heat as they change to a liquid state. The water gas that condenses on your mirror actually increases the temperature of that mirror. This is why steam can be quite dangerous. Not only is it hot to begin with, but if it condenses on your skin it releases even more heat which can give you severe burns. Objects absorb heat when they melt and evaporate/boil. Objects release heat when they freeze and condense.


Do you remember when I said that heat and temperature are two different things? Heat is energy – it is thermal energy. It can be transferred from one object to another by conduction, convection, and radiation. We’re now going to explore heat capacity and specific heat. Here’s what you do:


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You Need:


  • Balloon
  • Water
  • Matches, candle, and adult help
  • Sink


Download Student Worksheet & Exercises


1. Put the balloon under the faucet and fill the balloon with some water.


2. Now blow up the balloon and tie it, leaving the water in the balloon. You should have an inflated balloon with a tablespoon or two of water at the bottom of it.


3. Carefully light the match or candle and hold it under the part of the balloon where there is water.


4. Feel free to hold it there for a couple of seconds. You might want to do this over a sink or outside just in case!


So why didn’t the balloon pop? The water absorbed the heat! The water actually absorbed the heat coming from the match so that the rubber of the balloon couldn’t heat up enough to melt and pop the balloon. Water is very good at absorbing heat without increasing in temperature which is why it is used in car radiators and nuclear power plants. Whenever someone wants to keep something from getting too hot, they will often use water to absorb the heat.


Think of a dry sponge. Now imagine putting that sponge under a slowly running faucet. The sponge would continue to fill with water until it reached a certain point and then water started to drip from it. You could say that the sponge had a water capacity. It could hold so much water before it couldn’t hold any more and the water started dripping out. Heat capacity is similar. Heat capacity is how much heat an object can absorb before it increases in temperature. This is also referred to as specific heat. Specific heat is how much heat energy a mass of a material must absorb before it increases 1°C.


Exercises Answer the questions below:


  1. What is specific heat?
    1. The specific amount of heat any object can hold
    2. The amount of energy required to raise the temperature of an object by 1 degree Celsius.
    3. The type of heat energy an object emits
    4. The speed of a compound’s molecules at room temperature
  2. Name three ways thermal energy can be transferred from one object to another:
  3. At what point does the balloon pop?
  4. True or False: Water is poor at absorbing heat energy.
    1. True
    2. False

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Every time I’m served a hot bowl of soup or a cup of coffee with cream I love to sit and watch the convection currents. You may look a little silly staring at your soup but give it a try sometime!


Convection is a little more difficult to understand than conduction. Heat is transferred by convection by moving currents of a gas or a liquid. Hot air rises and cold air sinks. It turns out, that hot liquid rises and cold liquid sinks as well.


Room heaters generally work by convection. The heater heats up the air next to it which makes the air rise. As the air rises it pulls more air in to take its place which then heats up that air and makes it rise as well. As the air get close to the ceiling it may cool. The cooler air sinks to the ground and gets pulled back near the heat source. There it heats up again and rises back up.


This movement of heating and cooling air is convection and it can eventually heat an entire room or a pot of soup. This experiment should allow you to see convection currents.


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You need:


  • A pot
  • A stove with adult help
  • Pepper
  • Ice cubes
  • Food Coloring (optional)


1. Fill the pot about half way with water.


2. Put about a teaspoon of pepper into the water.


3. Put the pot on the stove and turn on the stove (be careful please).


4. Watch as the water increases in temperature. You should see the pepper moving. The pepper is moving due to the convection currents. If you look carefully you many notice pepper rising and falling.


5. Put an ice cube into the water and see what happens. You should see the pepper at the top of the water move towards the ice cube and then sink to the bottom of the pot as it is carried by the convection currents.


6. Just for fun, put another ice cube into the water, but this time drop a bit of food coloring on the ice cube. You should see the food coloring sink quickly to the bottom and spread out as it is carried by the convection currents.


Did you see the convection currents? Hot water rising in some areas of the pot and cold water sinking in other areas of the pot carried the pepper and food coloring throughout the pot. This rising and sinking transferred heat through all the water causing the water in the pot to increase in temperature.


Heat was transferred from the flame of the stove to the water by convection. More accurately, heat was transferred from the flame of the stove to the metal of the pot by conduction and then from the metal of the pot throughout the water through convection.


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