This experiment is for advanced students.

Lewis and Clark did this same experiment when they reached the Oregon coast in 1805. Men from the expedition traveled fifteen miles south of the fort they had built at the mouth of the Columbia River to where Seaside, Oregon now thrives.

In 1805, however, it was just men from the fort and Indians. They built an oven of rocks. For six weeks, they processed 1,400 gallons of seawater, boiling the water off to gain 28 gallons of salt.

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Lewis and Clark National Historic Park commemorates the struggles of the expedition. (The reconstructed fort is also there to visit.) It is Fort Clatsop National Memorial, and is quite an experience to go through the fort.

Lewis and Clark went to great lengths to obtain salt. The men had been complaining that fish without salt had become something to avoid. Salt is important to us as well. It is a condiment, an addition to food that brings out the food’s natural flavor. Besides its food value, salt is used as a food preservative. It destroys bacteria in food by removing moisture from their “bodies” and killing them.

Sodium chloride, table salt, NaCl….they’re all acceptable names for salt. If NaCl is broken down into its component elements, the elements don’t act like our friend salt. Its components are sodium and chlorine.

Sodium is a highly reactive alkali metal, element #11 on the periodic table. It is exothermic in water, which means that is gives of heat as it reacts with water. Small pieces tossed into water will react with it. The sodium particles give off heat that melts them into round balls. The sodium particles bounce and scurry around the surface at a high rate of speed. If you ever get the chance to observe this, do it. The reaction continues until the sodium is gone. Sodium, as it reacts with the water, changes chemically into sodium hydroxide. These cool things that sodium does are also dangerous. Sodium and sodium hydroxide are caustic…they are so pH basic that they will burn you.

Chlorine is a halogen, group 17, element #17. Chlorine is used in bleach, disinfectants, and in swimming pool maintenance. It seems that anywhere you want to remove color or life, chlorine is your element. This property of chlorine to kill was used in war. (It would react with the mucous linings in their throat, undergoing a chemical reaction to turn into hydrochloric acid in their throats. Hydrochloric acid is a very dangerous acid, usually fatal once inside you.) Chlorine is known as bleach at home. Never, never, drink it or breathe its fumes.

Materials:

• Goggles
• Gloves
• Jar or glass
• 2 90o glass tubes
• Chemistry stand
• Rubber tubing
• Test tube clamp
• Erlenmeyer flask
• One-hole rubber stopper
• Wire screen
• Alcohol burner
• Lighter
• Test tube
• Water
• Saltwater
• Heating rod

Look out for the hot flask and other glassware. Allow everything to cool before cleaning.

When done heating, move the rubber tubing out of the water. There is a difference in pressure between the heated glassware and the water bath. That difference in pressure will cause the water to enter the tubing and cool water will flow into the hot glassware and could cause catastrophic damage to the glassware.

Never…Never!….drink the results of an experiment. Yeah, I know that plain old water is supposed to be in the test tube, but follow the experiment’s safety guidelines. You’ve had other stuff in that test tube, too.

C3000: Experiment 83

Here’s what’s going on in this experiment:

That flask of saltwater will start to boil, and water vapor will leave the flask and travel to the test tube. There is no chemical change occurring in this experiment, but a physical one. A physical change involves a change in state (melting, freezing, vaporization, condensation, sublimation). Physical changes are things like crushing a can, melting an ice cube, breaking a bottle, or boiling saltwater until there is nothing left but salt and steam.

Cleanup: Clean everything thoroughly after you are finished with the lab. After cleaning with soap and water, rinse thoroughly. Chemists use the rule of “three” in cleaning glassware and tools. After washing, chemists rinse out all visible soap and then rinse three times more.

Storage: Place cleaned tools and glassware in their respective storage places.

Disposal: Liquids can be washed down the drain

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